Chemical characterization by ultrahigh-resolution mass spectrometry analysis of acid-extractable organics from produced water extracted by solvent-terminated dispersive liquid-liquid microextraction

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dc.creatorAguiar, Deborah Victória Alves de
dc.creatorSilva, Thais
dc.creatorBrito, Talita Pinheiro de
dc.creatorSantos, Gabriel Franco dos
dc.creatorCarvalho, Rogério Mesquita de
dc.creatorMedeiros Júnior, Iris
dc.creatorSimas, Rosineide Costa
dc.creatorVaz, Boniek Gontijo
dc.date.accessioned2023-07-28T15:11:22Z
dc.date.available2023-07-28T15:11:22Z
dc.date.issued2021
dc.description.abstractProduced water by the offshore oil industry represents a significant environmental problem due to the high volume generated and its toxicity. Therefore, new methods are necessary to characterize the produced water and, consequently, to provide an appropriate destination. Here, we used solvent-terminated dispersive liquid-liquid microextraction (ST-DLLME) followed by ultrahigh-resolution mass spectrometry (UHRMS) analysis to extract and characterize naphthenic acids (NAs) from produced water (PW). ST-DLLME is based on a ternary mixture of solvents classified as dispersive, extractor, and demulsifying solvents to ensure analyte extraction efficiency. After that, seven solvent systems at three pH values (2, 7, and 10) were used to study the influences of the sample pH and organic-phase polarity. The relationship between pKa and pH affects the equilibrium between ions and molecules in the aqueous phase, impacting the extraction efficiency. The results showed that at pH 2, the extractability of NAs is directly affected by the dielectric constant of the dispersive solvent. Therefore, when dichloromethane was employed as a dispersive solvent, ST-DLLME presented a better performance, and NA species within an extensive DBE range (1 – 8) and range of carbon numbers (C7 – C18) were extracted. At pH 7 and 10, the solvent system that employed cyclohexane as a nonpolar dispersive solvent demonstrated the highest extraction efficiency, whereas nonpolar NA species with a carbon number greater than C22 could be extracted. Moreover, solutions at pH 7 and 10 expressed more comprehensive molecular formulas for the corresponding compounds than those at pH 2. In summary, ST-DLLME has become a valuable analytical tool for extracting NAs from PW since this extraction technique minimizes the consumption of samples and solvents.pt_BR
dc.identifier.citationAGUIAR, Deborah V. A. et al. Chemical characterization by ultrahigh-resolution mass spectrometry analysis of acid-extractable organics from produced water extracted by solvent-terminated dispersive liquid-liquid microextraction. Fuel, Amsterdam, v. 306, e121573, 2021. DOI: 10.1016/j.fuel.2021.121573. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S001623612101454X?via%3Dihub. Acesso em: 28 jun. 2023.pt_BR
dc.identifier.doi10.1016/j.fuel.2021.121573
dc.identifier.issn0016-2361
dc.identifier.issne- 1873-7153
dc.identifier.urihttps://www.sciencedirect.com/science/article/abs/pii/S001623612101454X?via%3Dihub
dc.language.isoengpt_BR
dc.publisher.countryHolandapt_BR
dc.publisher.departmentInstituto de Química - IQ (RMG)pt_BR
dc.rightsAcesso Restritopt_BR
dc.titleChemical characterization by ultrahigh-resolution mass spectrometry analysis of acid-extractable organics from produced water extracted by solvent-terminated dispersive liquid-liquid microextractionpt_BR
dc.typeArtigopt_BR

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