Synthesis of Al-rich Beta zeolite through surface response design

Abstract

A central composite design was proposed to analyze the effects of temperature, time, and Si/Al and H2O/SiO2 ratios on the crystallization of Al-rich Beta framework. The proposed response variable was based on X-ray diffraction patterns of synthesized materials. Si/Al ratios of synthesized Beta zeolites were predominantly larger than those employed in synthesis gels, indicating loss of Si during sample washing. Crystal sizes of synthesized Beta zeolites tended to increase with decreasing values of Si/Al ratio. It was also found that crystallinity is inversely proportional to temperature and directly proportional to Si/Al ratio. However, this latter correlation is only valid for zeolites synthesized at H2O/SiO2 ratios lower than 15.22, a value that is independent of synthesis temperature and time. For H2O/SiO2 values larger than the respective threshold, crystallinity becomes inversely proportional to the Si/Al ratio.