A metalloligand approach for the self-assembly of a magnetic two-dimensional grid-of-grids

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dc.creatorKalinke, Lucas Hoffmann Greghi
dc.creatorGomes, Danielle Cangussu de Castro
dc.creatorLloret Pastor, Francesc
dc.creatorBruno, Rosaria
dc.creatorArmentano, Donatella
dc.creatorPardo Marín, Emilio
dc.creatorFerrando Soria, Jesús
dc.date.accessioned2023-10-17T14:45:47Z
dc.date.available2023-10-17T14:45:47Z
dc.date.issued2019
dc.description.abstractThe efficient organization of discrete functional molecules into extended frameworks, while retaining their physical properties, is a mandatory requisite to move toward applications. Here we describe the validity of the metalloligand design strategy as a versatile and powerful approach to build up a two-dimensional (2D) magnetic metal–organic framework (MOF) composed of preformed discrete antiferromagnetically coupled [3 × 3] Cu9II incomplete grids. In the first stage, a novel oxamato-based nonanuclear copper(II) complex has been self-assembled from the reaction of a polytopic organic ligand, with well-defined coordination pockets, with CuII ions. Then, the nonanuclear complex has been used as metalloligand toward calcium(II) cations to afford a CaII–CuII 2D MOF (1) with a grid-like topology and the magnetic properties of the preformed nonanuclear grids.
dc.identifier.citationKALINKE, Lucas H. G. et al. A metalloligand approach for the self-assembly of a magnetic two-dimensional grid-of-grids. Crystal Growth & Design, Washington, v. 19, n. 7, p. 3905-3912, 2019. DOI: 10.1021/acs.cgd.9b00324. Disponível em: https://pubs.acs.org/doi/10.1021/acs.cgd.9b00324. Acesso em: 29 set. 2023.
dc.identifier.doi10.1021/acs.cgd.9b00324
dc.identifier.issn1528-7483
dc.identifier.issne- 1528-7505
dc.identifier.urihttps://pubs.acs.org/doi/10.1021/acs.cgd.9b00324
dc.language.isoeng
dc.publisher.countryEstados unidos
dc.publisher.departmentInstituto de Química - IQ (RMG)
dc.rightsAcesso Restrito
dc.titleA metalloligand approach for the self-assembly of a magnetic two-dimensional grid-of-grids
dc.typeArtigo

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