A metalloligand approach for the self-assembly of a magnetic two-dimensional grid-of-grids
dc.creator | Kalinke, Lucas Hoffmann Greghi | |
dc.creator | Gomes, Danielle Cangussu de Castro | |
dc.creator | Lloret Pastor, Francesc | |
dc.creator | Bruno, Rosaria | |
dc.creator | Armentano, Donatella | |
dc.creator | Pardo Marín, Emilio | |
dc.creator | Ferrando Soria, Jesús | |
dc.date.accessioned | 2023-10-17T14:45:47Z | |
dc.date.available | 2023-10-17T14:45:47Z | |
dc.date.issued | 2019 | |
dc.description.abstract | The efficient organization of discrete functional molecules into extended frameworks, while retaining their physical properties, is a mandatory requisite to move toward applications. Here we describe the validity of the metalloligand design strategy as a versatile and powerful approach to build up a two-dimensional (2D) magnetic metal–organic framework (MOF) composed of preformed discrete antiferromagnetically coupled [3 × 3] Cu9II incomplete grids. In the first stage, a novel oxamato-based nonanuclear copper(II) complex has been self-assembled from the reaction of a polytopic organic ligand, with well-defined coordination pockets, with CuII ions. Then, the nonanuclear complex has been used as metalloligand toward calcium(II) cations to afford a CaII–CuII 2D MOF (1) with a grid-like topology and the magnetic properties of the preformed nonanuclear grids. | |
dc.identifier.citation | KALINKE, Lucas H. G. et al. A metalloligand approach for the self-assembly of a magnetic two-dimensional grid-of-grids. Crystal Growth & Design, Washington, v. 19, n. 7, p. 3905-3912, 2019. DOI: 10.1021/acs.cgd.9b00324. Disponível em: https://pubs.acs.org/doi/10.1021/acs.cgd.9b00324. Acesso em: 29 set. 2023. | |
dc.identifier.doi | 10.1021/acs.cgd.9b00324 | |
dc.identifier.issn | 1528-7483 | |
dc.identifier.issn | e- 1528-7505 | |
dc.identifier.uri | https://pubs.acs.org/doi/10.1021/acs.cgd.9b00324 | |
dc.language.iso | eng | |
dc.publisher.country | Estados unidos | |
dc.publisher.department | Instituto de Química - IQ (RMG) | |
dc.rights | Acesso Restrito | |
dc.title | A metalloligand approach for the self-assembly of a magnetic two-dimensional grid-of-grids | |
dc.type | Artigo |
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