Redetermination of bis(l-asparaginato)copper(II)
dc.creator | Vencato, Ivo | |
dc.creator | Lariucci, Carlito | |
dc.creator | Ferreira, Katiúscia Daiane | |
dc.creator | Santana, Ricardo Costa de | |
dc.creator | Carvalho, Jesiel Freitas | |
dc.date.accessioned | 2024-07-11T15:32:40Z | |
dc.date.available | 2024-07-11T15:32:40Z | |
dc.date.issued | 2004 | |
dc.description.abstract | The Cu atom of the title compound, [Cu(C4H7N2O3)2], is in a tetragonally distorted octahedral environment. A carboxyl O atom and the α-amino N atom from each ligand coordinate to Cu in a trans square-planar configuration [Cu—O = 2.003 (3) and 2.020 (3) Å, and Cu—N = 2.029 (4) and 2.049 (4) Å]. The octahedron is completed by bridging amide O atoms from adjacent molecules [Cu—O = 2.229 (4) Å and Cu—O = 2.885 (4) Å] separated by c translations. This arrangement creates infinite chains linked in the [001] direction, stabilized by intra- and intermolecular N—H...O bonds. The structure has already been published [Stephens, Vagg & Williams (1975). Acta Cryst. B31, 841–845]; this redetermination reports the structure with higher precision. | |
dc.identifier.citation | VENCATO, Ivo; LARIUCCI, Carlito; FERREIRA, Katiuscia D.; SANTANA, Ricardo C.; CARVALHO, Jesiel F. Redetermination of bis(l-asparaginato)copper(II). Acta Crystallographica Section E: crystallographic communications, New York, v. 60, n.10, p. m1428-m1430, 2004. DOI: 10.1107/S1600536804022202. Disponível em: https://journals.iucr.org/paper?buy=yes&cnor=bt6505&showscheme=yes&sing=yes. Acesso em: 26 maio 2026. | |
dc.identifier.doi | 10.1107/S1600536804022202 | |
dc.identifier.issn | e- 2056-9890 | |
dc.identifier.uri | https://journals.iucr.org/paper?buy=yes&cnor=bt6505&showscheme=yes&sing=yes | |
dc.language.iso | eng | |
dc.publisher.country | Estados unidos | |
dc.publisher.department | Instituto de Física - IF (RMG) | |
dc.rights | Acesso Restrito | |
dc.title | Redetermination of bis(l-asparaginato)copper(II) | |
dc.type | Artigo |
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