Synthesis, crystal structure and Hirshfeld analysis of [Zn(H2O)4(ampyz)2][Zn(H2O)6](SO4)2(H2O)2

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dc.creatorNascimento Neto, José Antônio do
dc.creatorValdo, Ana Karoline Silva Mendanha
dc.creatorSouza, Patricia da Cruz
dc.creatorMartins, Felipe Terra
dc.date.accessioned2023-11-27T15:24:50Z
dc.date.available2023-11-27T15:24:50Z
dc.date.issued2018
dc.description.abstractThe wide range of ligands and metals led to an extensive development of coordination chemistry. These compounds have been studied due to possible applications in several fields, as catalysis and nonlinear optics. The crystal structure of a coordination compound allows to establish a direct relation between structure and properties. Among the ligands, nitrogen aromatic compounds have been used largely in synthesis, since they enable strong coordination bond and stable intermolecular interactions, increasing also the possibility to study them in the crystalline state. This work reports the synthesis, crystal structure, infrared and UV-Vis spectroscopy of a Zn(II) complex with 2-aminopyrazine (ampyz) and water as ligands, resulting in the formula [Zn(H2O)4(ampyz)2][Zn(H2O)6](SO4)2(H2O)2. Moreover, to illustrate the intermolecular interactions, we also report the analysis of the Hirshfeld surface and its fingerprint for the main complex [Zn(H2O)4(ampyz)2]2+.
dc.identifier.citationNASCIMENTO NETO, José Antônio do et al. Synthesis, crystal structure and Hirshfeld analysis of [Zn(H2O)4(ampyz)2][Zn(H2O)6](SO4)2(H2O)2. Chemical Data Collections, Amsterdam, v. 17/18, p. 1-8, 2018. DOI: 10.1016/j.cdc.2018.07.003. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S2405830018301150?via%3Dihub. Acesso em: 27 nov. 2023.
dc.identifier.doi10.1016/j.cdc.2018.07.003
dc.identifier.issne- 2405-8300
dc.identifier.urihttps://www.sciencedirect.com/science/article/abs/pii/S2405830018301150?via%3Dihub
dc.language.isoeng
dc.publisher.countryGra-bretanha
dc.publisher.departmentInstituto de Química - IQ (RMG)
dc.rightsAcesso Restrito
dc.subjectSingle crystal structure
dc.subjectX-Ray diffraction
dc.subject2-aminopyrazine
dc.subjectCoordination compound
dc.subjectIntermolecular interactions
dc.titleSynthesis, crystal structure and Hirshfeld analysis of [Zn(H2O)4(ampyz)2][Zn(H2O)6](SO4)2(H2O)2
dc.typeArtigo

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